From IEEE Spectrum, August 1, 2024:
The Saga of AD-X2, the Battery Additive That Roiled the NBS
In the David vs. Goliath struggle over AD-X2, would science win?
Senate hearings, a post office ban, the resignation of the director of the National Bureau of Standards, and his reinstatement after more than 400 scientists threatened to resign. Who knew a little box of salt could stir up such drama?
What was AD-X2?
It all started in 1947 when a bulldozer operator with a 6th grade education, Jess M. Ritchie, teamed up with UC Berkeley chemistry professor Merle Randall to promote AD-X2, an additive to extend the life of lead-acid batteries. The problem of these rechargeable batteries’ dwindling capacity was well known. If AD-X2 worked as advertised, millions of car owners would save money.A basic lead-acid battery has two electrodes, one of lead and the other of lead dioxide, immersed in dilute sulfuric acid. When power is drawn from the battery, the chemical reaction splits the acid molecules, and lead sulfate is deposited in the solution. When the battery is charged, the chemical process reverses, returning the electrodes to their original state—almost. Each time the cell is discharged, the lead sulfate “hardens” and less of it can dissolve in the sulfuric acid. Over time, it flakes off, and the battery loses capacity until it’s dead.
By the 1930s, so many companies had come up with battery additives that the U.S. National Bureau of Standards stepped in. Its lab tests revealed that most were variations of salt mixtures, such as sodium and magnesium sulfates. Although the additives might help the battery charge faster, they didn’t extend battery life. In May 1931, NBS (now the National Institute of Standards and Technology, or NIST) summarized its findings in Letter Circular No. 302: “No case has been found in which this fundamental reaction is materially altered by the use of these battery compounds and solutions.”
Of course, innovation never stops. Entrepreneurs kept bringing new battery additives to market, and the NBS kept testing them and finding them ineffective.
Do battery additives work?....
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